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Dilute acid/metal salt hydrolysis of lignocellulosics

Published online: Apr 27, 2009

Geographical region Europe
Subject Lignocellulosic hydrolysis
Issue date Apr 1, 2009
Title Dilute acid/metal salt hydrolysis of lignocellulosics
Patent Number EP1307576 B1
Patent Application Number EP1307576 A1
Assignee Midwest Research Inst, USA
Relevance A method for hydrolyzing lignocellulosic material under conditions to obtain higher fermentable sugars involving dilute acid hydrolysis process.
Type of claims Grant
Overview This patent discloses a process for converting lignocellulosic biomass such as softwood, hardwood into fermentable sugars by acid impregnated biomass particles. The advantage of the process includes reduction in the cost of steam and equipment, limits the degradation of desirable sugars and formation of toxic byproducts due to kinetic constraints and provides complete hydrolysis of the lignocellulosic substrate. The process comprises, A) impregnating a lignocellulosic feedstock with a mixture of an amount of aqueous solution of a dilute acid catalyst and a metallic salt catalyst sufficient to hydrolyze hemicellulose and cellulose fractions to provide higher overall fermentable sugar yields than is obtainable hydrolyzing with dilute acid alone, B) loading the impregnated lignocellulosic feedstock into a reactor and heating at a temperature of between 120°C to 240°C for 1 to 30 minutes and cooling the impregnated lignocellulosic feedstock and mixture of aqueous solution of dilute acid catalyst (H2SO4, HCl, etc) and metallic salt catalyst (ferrous sulfate, aluminium sulfate, etc) to less than 105°C and C) recovering the water soluble sugars.
Related patent documents US Patent publications

US4529699 - Process and installation for obtaining ethanol by the continuous acid hydrolysis of cellulosic materials (1985)
US4520105 - Process for production of sugars and optionally cellulose and lignin from lignocellulosic raw materials (1985)
US5411594 - Bei hydrolysis process system an improved process for the continuous hydrolysis saccharification of ligno-cellulosics in a two-stage plug-flow-reactor system (1995)
US5536325 - Method of treating biomass material (1996)
US6022419 - Hydrolysis and fractionation of lignocellulosic biomass (2000)
US5879463 - Process for rapid acid hydrolysis of lignocellulosic material and hydrolysis reactor (1999)

Foreign patent publications

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